کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1281963 | 1497538 | 2013 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Optimization of surface charge transfer processes on rutile TiO2 nanorods photoanodes for water splitting Optimization of surface charge transfer processes on rutile TiO2 nanorods photoanodes for water splitting](/preview/png/1281963.png)
Electrochemical impedance spectroscopy (EIS) has been performed to investigate the photocatalytic properties of titanium dioxide nanorods in a photoelectrochemical water splitting system. A two-channel transmission line model has been proposed to interpret the frequency response of the main charge transfer processes that occur at nanorod/electrolyte and platinum/electrolyte interfaces. EIS was then employed to determine that the dramatic effect of the annealing treatment on the photocurrent density had its origin on a poor charge transfer at the titania/electrolyte interface. X-ray photoelectron spectroscopy and thermogravimetry measurements have been used to prove the relevance of the presence of chlorine coming from the synthesis process of TiO2 nanorods.
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► TiO2 nanorods exhibit high photoelectrochemical efficiency under sunlight.
► The efficiency is strongly affected by a final heat treatment step during synthesis.
► Residual chlorine species from the synthesis process block the reaction sites.
► Heating above 250 °C under O2 needed to completely remove residual chlorine species.
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 7, 7 March 2013, Pages 2979–2985