کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1282362 1497565 2012 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nanostructured rapidly solidified LaMg11Ni alloy: Microstructure, crystal structure and hydrogenation properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Nanostructured rapidly solidified LaMg11Ni alloy: Microstructure, crystal structure and hydrogenation properties
چکیده انگلیسی

In our earlier publication (Poletaev et al., J Alloys Compd., 509S (2011) S633) we reported a drastic variation of the structural and hydrogenation properties of LaMg∼12 intermetallic alloy caused by Rapid Solidification (RS). In present work we have probed the effect of nickel during the chemical modification of LaMg12, in combination with RS, on the structure, microstructure and hydrogen absorption–desorption properties of the alloys.RS was performed at three solidification rates, 300–2000 rpm. Ni was found to form a solid solution replacing both La and Mg to yield La1.7Mg16.7Ni0.6 intermetallic. With increasing RS cooling rates, the very fine, almost amorphous microstructures were formed. The LaMg11Ni alloy solidified at the highest cooling rate exhibited the fastest hydrogenation kinetics, reaching maximum hydrogenation capacity of 5.02 wt. % H. Studies of the hydrogenated RS ribbons showed the formation of the nano-scale embryos of MgH2, growing to form polyhedral grains of magnesium dihydride.

Figure optionsDownload as PowerPoint slideHighlights
► RS results in a structural disorder developing with increasing solidification rate.
► In La2Mg17 Ni partially substitutes both La and Mg to form La1.7Mg16.7Ni0.6.
► Higher quenching rates result in better hydrogen absorption–desorption kinetics.
► Formation of the nano-scale embryos of MgH2 in the hydrogenated RS ribbons.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 37, Issue 4, February 2012, Pages 3548–3557
نویسندگان
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