کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1282936 | 1497609 | 2010 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal expansion and electrochemical properties of Ni-doped GdBaCo2O5+δ double-perovskite type oxides
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Layered GdBaCo2 âx NixO5 + δ (0 â¤Â x â¤Â 0.3) complex oxides were synthesized and investigated as cathodes for intermediate-temperature solid oxide fuel cell (IT-SOFCs). All compositions formed an orthorhombic double-perovskite structure after calcination at 1000 °C for 5 h. The thermal expansion coefficient (TEC) was effectively decreased due to the partial substitution of Ni for Co, but the cathodic polarization resistance slightly increased with the increasing Ni content. Among the tested oxides, the GdBaCo1.7Ni0.3O5 + δ composition showed a fairly reduced TEC (15.5 Ã 10â6 Kâ1) and reasonably low polarization resistances (e.g., 0.54 Ωcm2 at 600 °C), which was considered as a promising candidate for IT-SOFCs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 8, April 2010, Pages 3775-3782
Journal: International Journal of Hydrogen Energy - Volume 35, Issue 8, April 2010, Pages 3775-3782
نویسندگان
Bo Wei, Zhe Lü, Dechang Jia, Xiqiang Huang, Yaohui Zhang, Wenhui Su,