کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1283829 1497934 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Origin of hysteresis between charge and discharge processes in lithium-rich layer-structured cathode material for lithium-ion battery
ترجمه فارسی عنوان
منشاء هیستریزی بین فرایندهای شارژ و تخلیه در مواد کاتدی لایه ای غنی از لیتیم برای باتری لیتیوم یون
کلمات کلیدی
باتری یون لیتیوم، مواد کاتد ساختار لایه دار غنی از لیتیم، پتانسیل مدار، هیسترزیس، اکسیداسیون حالت، ساختار کریستالی
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
چکیده انگلیسی


• There is large hysteresis between charge and discharge curves in Li1.2Ni0.13Mn0.54Co0.13O2.
• Lattice parameter at the same SOC differs in charge and discharge processes.
• Oxidation state of each element at the same SOC differs in charge and discharge processes.

There is large hysteresis between charge and discharge curves in lithium-rich layer-structured cathode material, Li1.2Ni0.13Mn0.54Co0.13O2. The mechanism for hysteresis was examined by X-ray diffraction (XRD) and X-ray absorption fine structure (XAFS) measurement as a first step in solving this issue. XRD measurements clarified that there was hysteresis in the lattice parameter between charge and discharge processes. XAFS spectra indicated that transition metals were oxidized and reduced in the same potential region during charge and discharge processes. Oxygen was oxidized at higher potential than transition metals during charge process; however, the former was reduced at lower potential than the latter during discharge process. Therefore, large hysteresis of potential between charge and discharge processes in Li1.2Ni0.13Mn0.54Co0.13O2 was mainly related to the reaction which is compensated with redox of oxygen.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 298, 1 December 2015, Pages 144–149
نویسندگان
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