کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1284145 | 1497972 | 2014 | 5 صفحه PDF | دانلود رایگان |
• Nickel and platinum were used to prepare a series of core@shell nano-structures.
• The core@shell nano-structures were used for catalytic dehydrogenation of N2H4BH3.
• Ni5@Pt permitted to generate 4.5 mol H2 + N2 per mol N2H4BH3 at 50 °C.
• The efficiency of Ni5@Pt is due to the presence of both metals on the surface.
• The core@shell nano-catalysts have accordingly the structure Ni@NiPt.
Nickel and platinum were used to prepare a series of core@shell structures to be studied as catalysts for the dehydrogenation of aqueous hydrazine borane N2H4BH3 at 50 °C. The challenge was especially to get a maximum of 3 mol of gas by decomposition of the N2H4 moiety. In our conditions, the most efficient Ni@Pt was found to be the structure constituted of 5 atoms of nickel for 1 atom of platinum. This catalyst permits to generate up to 4.5 mol H2 + N2. Surface characterizations showed that the efficiency of this catalyst is due to the presence of both metals on the surface, suggesting therefore that the structure would be rather Ni@NiPt. Our main results are reported herein.
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Journal: Journal of Power Sources - Volume 260, 15 August 2014, Pages 77–81