کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1284229 | 1497977 | 2014 | 9 صفحه PDF | دانلود رایگان |

• A facile approach is proposed to fabricate all-solid-state supercapacitors.
• MnFe2O4/graphene hybrids achieve a capacitance of 300 F g−1 at 0.3 A g−1.
• Our devices show excellent electrochemical performance and cycling stability.
A critical challenge for the construction of flexible electrochemical capacitors is the preparation of flexible electrodes with large specific capacitance and robust mechanical strength. Here, we demonstrate a facile approach to make high performance and flexible electrodes by dropping MnFe2O4/graphene hybrid inks onto flexible graphite sheets (as current collectors and substrates) and drying under an infrared lamp. MnFe2O4/graphene hybrid inks are synthesized by immobilizing the MnFe2O4 microspheres on the graphene nanosheets via a simple solvothermal route. Electrochemical studies show that MnFe2O4/graphene exhibits a high capacitance of 300 F g−1 at a current density of 0.3 A g−1. In addition, the excellent electrochemical performance of a supercapacitor consisting of a sandwich structure of two pieces of MnFe2O4/graphene hybrids modified electrodes separated by polyvinyl alcohol (PVA)-H2SO4 gel electrolyte is further explored. Our studies reveal that the flexible supercapacitor device with 227 μm thickness can achieve a maximum specific capacitance of 120 F g−1 at a current density of 0.1 A g−1 and excellent cycle performance retaining 105% capacitance after 5000 cycles. This research may offer a method for the fabrication of lightweight, stable, flexible and high performance energy storage devices.
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Journal: Journal of Power Sources - Volume 255, 1 June 2014, Pages 170–178