کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1285575 | 973149 | 2008 | 7 صفحه PDF | دانلود رایگان |
A novel non-noble electrocatalyst with an average particle size of approximately 4 nm was prepared by heat-treating carbon-supported molybdenum tetraphenylporphyrin in a flow NH3 atmosphere. The effects of heating time and temperature on its electrocatalystic properties were investigated. The samples obtained were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, and EDX. The results show that the synthesized catalyst has the same composition as that of MoN. This carbon-supported catalyst displays a strong activity towards oxygen reduction reaction (ORR) and a methanol-tolerant property. The catalyzed ORR proceeds by an approximate four-electron reduction pathway from O2 directly to H2O.
Journal: Journal of Power Sources - Volume 177, Issue 2, 1 March 2008, Pages 296–302