کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1285741 | 1497929 | 2016 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Improving cycling performance of Li-rich layered cathode materials through combination of Al2O3-based surface modification and stepwise precycling Improving cycling performance of Li-rich layered cathode materials through combination of Al2O3-based surface modification and stepwise precycling](/preview/png/1285741.png)
• Al2O3-coated Li[Li0.2Ni0.18Co0.03Mn0.58]O2 was synthesized and investigated.
• The surface-modification layer is composed of Li–Al oxides and Al oxides.
• An interlayer formed between the modification layer and Li[Li0.2Ni0.18Co0.03Mn0.58]O2 particles.
• A discharge capacity >310 mA h−1 and excellent cycling stability at 50 °C are achieved.
Controlling a cathode/electrolyte interface by modifying the surface of a cathode material with metal oxides or phosphates is a concept being explored as a possible strategy for improving the electrochemical performance of such materials. This study therefore looks at the crystal structure and chemical bonding state from bulk to surface of Al2O3-coated Li[Li0.2Ni0.18Co0.03Mn0.58]O2 and explores the influence that surface modification has on the electrochemical performance. Investigation by X-ray diffraction, hard X-ray photoelectron spectroscopy (HAXPES) and galvanostatic charge/discharge reaction reveals that the surface-modification layer is composed of Li–Al oxides and Al oxides, with a LiM1−xAlxO2 (M = transition metal) interlayer formed between the modification layer and Li[Li0.2Ni0.18Co0.03Mn0.58]O2 particles. The cycling performance of the Li-rich layered oxide is enhanced by its surface modification with Al2O3, achieving a discharge capacity of more than 310 mA h−1 and excellent cycling stability at 50 °C when combined with a more gradual Li-insertion/de-insertion process (i.e., stepwise precycling treatment).
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Journal: Journal of Power Sources - Volume 303, 30 January 2016, Pages 250–256