کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1285989 | 973169 | 2007 | 5 صفحه PDF | دانلود رایگان |
Microscopic magnetism of the electrochemically Li-deintercaleted LixCoO2 powders has been investigated by muon-spin rotation and relaxation (μ+SR) spectroscopy in the temperature (T) range between 10 and 300 K. Weak transverse-field μ+SR measurements indicate that localized moments appear in LiCoO2 below 60 K, while both Li0.53CoO2 and Li0.04CoO2 are paramagnetic even at 10 K. Zero-field μ+SR measurements for the samples with x = 0.53 and 0.04 show that the field distribution width (Δ) due to randomly oriented nuclear magnetic moments of 7Li and 59Co decreases monotonically with increasing T up to 250 K, and then it decreases steeper (increasing slope (dΔ/dT)) above 250 K. Because the muon hopping rate (ν) is almost T independent for Li0.53CoO2 below 300 K, the decrease in Δ suggests that the time scale of Li+ diffusion in LixCoO2 is within a microsecond scale.
Journal: Journal of Power Sources - Volume 174, Issue 2, 6 December 2007, Pages 711–715