کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1286499 | 1497969 | 2014 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Beneficial effects of 1-propylphosphonic acid cyclic anhydride as an electrolyte additive on the electrochemical properties of LiNi0.5Mn1.5O4 cathode material Beneficial effects of 1-propylphosphonic acid cyclic anhydride as an electrolyte additive on the electrochemical properties of LiNi0.5Mn1.5O4 cathode material](/preview/png/1286499.png)
• 1-Propylphosphonic acid cyclic anhydride (PACA) is investigated as an additive.
• Self-discharge of LiNi0.5Mn1.5O4 is effectively suppressed by adding PACA into electrolyte.
• Enhanced cycling performance of LiNi0.5Mn1.5O4 at elevated temperatures is achieved.
• Reduced transition metal dissolution of LiNi0.5Mn1.5O4 by using PACA.
Self-discharge and transition metal dissolution weaknesses bother the application of LiNi0.5Mn1.5O4 cathode material due to the severe oxidation of electrolyte at the high voltage state. A novel additive, 1-propylphosphonic acid cyclic anhydride (PACA), is desirable to prevent this oxidation. CV and charge–discharge results reveal that adding 0.5% PACA can relieve the oxidation of electrolyte. Consequently, the self-discharge and transition metal dissolution are both suppressed effectively, which is validated by self-discharge tests, XPS, and EDX analyses. Moreover, using PACA as an additive enhances the capacity retention capability of LiNi0.5Mn1.5O4 at elevated temperatures significantly.
Journal: Journal of Power Sources - Volume 263, 1 October 2014, Pages 231–238