کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1286661 | 1497965 | 2014 | 8 صفحه PDF | دانلود رایگان |
• Polyaniline with brachyplast structure was electropolymerized and characterized.
• The polyaniline acted as the sensitizer and p-type HTM for the ass-PSSC.
• The ass-PSSC delivered a photovoltaic conversion efficiency of 7.34%.
• The ass-PSSC demonstrated a good long-term stability after 1000 h.
High performance dual function of polyaniline (PANI) with brachyplast structure is synthesized by using a two-step cyclic voltammetry (CV) approach onto the fluorinated tin oxide (FTO) glass substrate, which acts as the sensitizer and p-type hole-transporting material (p-HTM) for the all-solid-state perovskite-sensitized solar cell (ass-PSSC) due to its π–π* transition and the localized polaron. The ass-PSSC based on the PANI delivers a photovoltaic conversion efficiency of 7.34%, and reduces from 7.34% to 6.71% after 1000 h, thereby 91.42% of the energy conversion efficiency is kept, indicating the device has a good long-term stability.
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Journal: Journal of Power Sources - Volume 267, 1 December 2014, Pages 1–8