کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1286780 | 1497966 | 2014 | 8 صفحه PDF | دانلود رایگان |
• A method is proposed to prepare cross-linked PVA–H2SO4 porous gel electrolyte.
• PVA porous membranes possess higher swelling ratio to H2SO4 aqueous solution.
• Graphene/CB films exhibit improved specific capacitance compared to graphene film.
• A flexible SC based on PVA porous gel electrolyte shows good performance at 70 °C.
Flexible all-solid-state supercapacitors (SCs) are fabricated using graphene/carbon black nanoparticle (GCB) film electrodes and cross-linked poly(vinyl alcohol)–H2SO4 porous gel electrolytes (gPVAP–H2SO4). The GCB composite films, with carbon black (CB) nanoparticles uniformly distributed in the graphene nanosheets, greatly improve the active surface areas and ion transportation of pristine graphene film. The porous structure of as-prepared gPVAP–H2SO4 membrane improves the equilibrium swelling ratio in electrolyte and provides interconnected ion transport channels. The chemical crosslinking solves the fluidity problem of PVA–H2SO4 gel electrolyte at high temperature. As-fabricated GCB//gPVAP(20)–H2SO4//GCB flexible SC displays an increased specific capacitance (144.5 F g−1 at 0.5 A g−1) and a higher specific capacitance retention (67.9% from 0.2 to 4 A g−1). More importantly, the flexible SC possesses good electrochemical performance at high temperature (capacitance retention of 78.3% after 1000 cycles at 70 °C).
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Journal: Journal of Power Sources - Volume 266, 15 November 2014, Pages 488–495