کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1287513 | 1497988 | 2013 | 4 صفحه PDF | دانلود رایگان |
The electronic structural changes during lithium-ion intercalation/de-intercalation process of nickel substituted lithium manganese spinel oxides have been investigated by using X-ray absorption near-edge structure (XANES) spectra of O K-edges as well as Ni L3-edges and Mn L3-edges. The results of the XANES spectra indicate that the electronic structure of both manganese and oxygen atoms contribute on the redox reaction at 0.06 ≤ x < 1, and only that of nickel atom affect the redox reaction at 1 < x ≤ 1.78 in LixNi0.5Mn1.5O4. Thus, the electronic structural change of oxygen atom is also crucial for considering redox reaction at intercalation/de-intercalation process, and the contribution of the oxygen atom on redox reaction differs in various redox cation species.
► Soft XANES techniques reveal the change of hybridized LUMO in LixNi0.5Mn1.5O4.
► Electronic structure of O is crucial for considering redox reaction of batteries.
► Contribution of the O on redox reaction differs in various cation species.
Journal: Journal of Power Sources - Volume 244, 15 December 2013, Pages 544–547