کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1287614 | 973228 | 2006 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Effect of (Al, Mg) substitution in LiNiO2 electrode for lithium batteries Effect of (Al, Mg) substitution in LiNiO2 electrode for lithium batteries](/preview/png/1287614.png)
Stabilized lithium nickelate is receiving increased attention as a low-cost alternative to the LiCoO2 cathode now used in rechargeable lithium batteries. Layered LiNi1−x−yMxMyO2 samples (Mx = Al3+ and My = Mg2+, where x = 0.05, 0.10 and y = 0.02, 0.05) are prepared by the refluxing method using acetic acid at 750 °C under an oxygen stream, and are subsequently subjected to powder X-ray diffraction analysis and coin-cell tests. The co-doped LiNi1−x−yAlxMgyO2 samples show good structural stability and electrochemical performance. The LiNiAl0.05Mg0.05O2, cathode material exhibits a reversible capacity of 180 mA h g−1 after extended cycling. These results suggest that the threshold concentration for aluminum and magnesium substitution is of the order of 5%. The co-substitution of magnesium and aluminium into lithium nickelate is considered to yield a promising cathode material.
Journal: Journal of Power Sources - Volume 158, Issue 1, 14 July 2006, Pages 641–645