کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1287684 | 1498009 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Needle-shaped 3D dye-sensitized solar cells using anodized Ti wire and Pt nanoparticle/carbon fiber electrodes Needle-shaped 3D dye-sensitized solar cells using anodized Ti wire and Pt nanoparticle/carbon fiber electrodes](/preview/png/1287684.png)
Needle-shaped dye-sensitized solar cells are developed using anodized Ti wire and carbon fiber with Pt nanoparticle. The model cell is composed of N719 dye-sensitized TiO2 nanotubes/Ti wire as working electrode, Pt nanoparticle/carbon fiber as a counter electrode and I−/I3− electrolyte encased in a capillary glass tube with internal diameter of 1.0 mm and 40 mm in length. The as-prepared DSSC looks like a needle leaf of pine tree. The energy conversion efficiency is 2.21% which can be up to 3.07% after TiCl4 post-treatment of photoanodes. In addition, higher current and output power can be obtained by parallel connection. Pt nanoparticle/carbon fiber is firstly used as counter electrode and the cyclic voltammetries investigation show that Pt nanoparticle/carbon fiber possess higher catalytic activity than Pt wire. Such type DSSC is TCO free and may be capable of achieving a long distance transport of photocurrent and harvesting all light from any direction in surroundings to generate electricity. It has been demonstrated that needle-shaped structure may be a good choice for a solar cell.
Needle-shaped dye-sensitized solar cells were successfully developed using anodized Ti wire and Pt/carbon fiber. TiCl4 post-treatment of photoanode, high catalysis performance of Pt/carbon fiber and the parallel connected of the as prepared DSSCs with two and three cell units were investigated. Figure optionsDownload as PowerPoint slideHighlights
► Needle-shaped dye-sensitized solar cells were developed using anodized Ti wire and Pt nanoparticle/carbon fiber.
► Pt nanoparticle/carbon fiber electrode exhibited high catalysis performance toward I3−.
► We explored its potential application in parallel connected situation.
► Carbon fiber was first employed as conductive substrate for counter electrode.
Journal: Journal of Power Sources - Volume 223, 1 February 2013, Pages 74–78