کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1287817 1497996 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide-based organic electrolyte for high performance lithium–sulfur batteries
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
N-Methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide-based organic electrolyte for high performance lithium–sulfur batteries
چکیده انگلیسی

Development of lithium–sulfur (Li–S) batteries has suffered from insufficient capacity and poor cycle-life. One of the reasons for these drawbacks is loss of active material, which is associated with the rapid diffusion of highly soluble lithium polysulfides formed as intermediates of discharge products in organic electrolytes, resulting in internal shuttling of lithium polysulfides. The diffusion of lithium polysulfides is determined largely by the physicochemical properties of electrolytes. Therefore, design of the physicochemical properties of the electrolyte to restrain the internal shuttling is vital to promote high performance for Li–S batteries. Here we present a newly designed room temperature ionic liquid (RTIL)-based organic electrolyte for Li–S battery. Our electrolyte provides a trade-off between solubility and diffusion rate of lithium polysulfides by mixing very different physicochemical properties of two solvents: high lithium polysulfide solubility of 1,2-dimethoxyethane (DME), and high viscosity of N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13-TFSI). An adequate composition ratio of mixed PP13-TFSI/DME afforded large capacity, high Coulombic efficiency, improved capacity retention, and suppressed internal shuttling.

A newly designed room temperature ionic liquid (RTIL)-based organic lithium electrolyte providing a trade-off between solubility and diffusion rate of lithium polysulfides by mixing N-methyl-N-propylpiperidinium bis(trifluoromethanesulfonyl)imide (PP13-TFSI) and DME with an optimal composition ratio was effectively employed in the Li–S battery, which achieved a large capacity of ∼1000 mA h g−1 at 0.2 C, a high Coulombic efficiency of almost 100%, and an improved capacity retention of ∼90% over 50 cycles in addition to slow internal shuttling.Figure optionsDownload as PowerPoint slideHighlights
► Design of PP13-TFSI/DME electrolyte for Li–S batteries.
► Suppression of internal shuttling using PP13-TFSI/DME.
► Achievement of reliable performance of Li–S batteries with PP13-TFSI/DME.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 236, 15 August 2013, Pages 207–214
نویسندگان
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