High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC) – A review

One possible solution of combating issues posed by climate change is the use of the High Temperature (HT) Polymer Electrolyte Membrane (PEM) Fuel Cell (FC) in some applications. The typical HT-PEMFC operating temperatures are in the range of 100–200 °C which allows for co-generation of heat and power, high tolerance to fuel impurities and simpler system design. This paper reviews the current literature concerning the HT-PEMFC, ranging from cell materials to stack and stack testing. Only acid doped PBI membranes meet the US DOE (Department of Energy) targets for high temperature membranes operating under no humidification on both anode and cathode sides (barring the durability). This eliminates the stringent requirement for humidity however, they have many potential drawbacks including increased degradation, leaching of acid and incompatibility with current state-of-the-art fuel cell materials. In this type of fuel cell, the choice of membrane material determines the other fuel cell component material composition, for example when using an acid doped system, the flow field plate material must be carefully selected to take into account the advanced degradation. Novel research is required in all aspects of the fuel cell components in order to ensure that they meet stringent durability requirements for mobile applications.

► We examine the state of the art developments for the High Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFC).
► We review the current literature concerning the HT-PEMFC ranging from the cell materials to the stack and stack testing.
► Advantages of HT-PEMFC type of system as compared with standard PEMFCs are discussed.
► The need for further research in this field, in order to fulfil those systems potential, is highlighted.