کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1288008 | 1498001 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Facile solid-state synthesis of Li2MnSiO4/C nanocomposite as a superior cathode with a long cycle life Facile solid-state synthesis of Li2MnSiO4/C nanocomposite as a superior cathode with a long cycle life](/preview/png/1288008.png)
The Li2MnSiO4/C nanocomposite has been successfully synthesized at a relatively low temperature of 650 °C by a facile solid-state reaction using citric acid as the carbon source. The highly crystalline Li2MnSiO4 nanoparticles in the size of 20–50 nm are coated by a uniform carbon layer in a thickness of 2–5 nm. At a rate of 0.05 C, the Li2MnSiO4/C nanocomposite exhibits a discharge specific capacity as high as 268 mAh g−1 for the first cycle and a reversible capacity of about 136 mAh g−1 after 140 cycles at room temperature. Meanwhile, an improved rate performance is achieved by the Li2MnSiO4/C nanocomposite. These superior electrochemical properties could be attributed to the nanoscale particle size and the enhanced electronic conductivity.
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► Li2MnSiO4/C nanocomposite is synthesized by a facile solid-state reaction.
► The typical size of Li2MnSiO4 nanoparticles is in the range of 20–50 nm
► The nanocomposite exhibits a discharge capacity of 136 mAh g−1 after 140 cycles.
► The nanocomposite also shows a greatly improved rate performance.
Journal: Journal of Power Sources - Volume 231, 1 June 2013, Pages 39–43