کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1288174 1498027 2012 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Film-shaped sol–gel Li4Ti5O12 electrode for lithium-ion microbatteries
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Film-shaped sol–gel Li4Ti5O12 electrode for lithium-ion microbatteries
چکیده انگلیسی

Homogeneous and transparent film-shaped spinel Li4Ti5O12 electrodes on gold coated quartz were synthesized by sol–gel and a dipping procedure after thermal treatments at 700 °C. The influence of the lithium precursor content on the phase composition, structure and electrochemical behavior of this material was studied. Spectral ellipsometry measurements and SEM-EDX analysis indicate an average thickness between 385 and 560 nm. Rutile TiO2 is detected using grazing incidence X-ray analysis and Micro-Raman in compositions with a lower content of lithium. Good galvanostatic cycling and very flat discharge–charge profiles confirm the high purity of Li4Ti5O12 electrodes obtained with the higher lithium content composition.


► Nanostructured Li4Ti5O12 thin film electrodes for Li-ion microbatteries were developed.
► Li4Ti5O12 thin films were produced by sol–gel method and dip-coating process.
► Composition Li/Ti = 6/5 presents single face-centered cubic spinel phase Li4Ti5O12.
► Good galvanostatic cycling and very flat discharge–charge were obtained.
► Li4Ti5O12 thin films are potential anode materials for lithium-ion microbatteries.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 205, 1 May 2012, Pages 491–494
نویسندگان
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