کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1288415 1498034 2012 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Porous Li2FeSiO4/C nanocomposite as the cathode material of lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Porous Li2FeSiO4/C nanocomposite as the cathode material of lithium-ion batteries
چکیده انگلیسی

In this paper, we report on the facile preparation of porous Li2FeSiO4/C nanocomposites by tartaric acid-assisted sol–gel method and their electrochemical properties as the cathode materials of Li-ion batteries. The structure, morphology, and texture of the as-prepared samples are characterized by means of XRD, Raman, SEM, TEM/HRTEM, and N2 adsorption/desorption techniques. The results show that the porous Li2FeSiO4/C nanocomposites are consisted of nanoparticles, which have been coated with in situ carbon on the surface. The electrochemical properties of the as-prepared Li2FeSiO4/C nanocomposites have been investigated using galvanostatic charge/discharge and cyclic voltammograms. It is found that porous Li2FeSiO4/C nanocomposite with 8.06 wt% carbon shows a high capacity of 176.8 mAh g−1 at 0.5 C in the first cycle and a reversible capacity of 132.1 mAh g−1 at 1 C (1 C = 160 mA g−1) in the 50th cycle. This high capacity indicates that more than one electron reaction may be occurred. These results illustrate that the porous Li2FeSiO4/C nanocomposite with 8.06 wt% carbon is potential in the application of high-rate cathode material of Li-ion batteries.


► Porous Li2FeSiO4/C nanocomposites have been synthesized by a simple sol–gel method.
► The as-synthesized porous Li2FeSiO4/C nanocomposites exhibit enhanced electronic conductivity and Li+ diffusion coefficient as well as superior rate and cycling capabilities.
► The porous Li2FeSiO4/C nanocomposite with 8.06 wt% carbon delivers a high initial discharge capacity of 176.8 mAh g−1 at 0.5 C (1 C = 160 mA g−1) and a reversible capacity of 132.1 mAh g−1 in the 50th cycle at 1 C.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 198, 15 January 2012, Pages 229–235
نویسندگان
, , , , , , ,