کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1288569 | 1498030 | 2012 | 8 صفحه PDF | دانلود رایگان |

In this work, a CoSb-nanocrystal/graphene hybrid nanostructure has been synthesized by a facile one-pot in situ solvothermal route. X-ray diffraction and X-ray photoelectron spectroscopy analyses show that the formation of CoSb alloy (CoSb or CoSb2) and the reduction of graphite oxide occur simultaneously during the one-pot solvothermal process. Scanning electron microscopy and transmission electron microscopy observations indicate that quasi-spheric CoSb (or CoSb2) nanoparticles with a size of 10–30 nm are uniformly anchored on graphene, forming a unique layered structure. The presence of graphene prevents the nanoparticles from aggregating. The attached alloy nanoparticles also hinder the restacking of the graphene sheets. The electrochemical measurements have shown that CoSb-nanocrystal/graphene nanocomposites exhibit improved electrochemical Li-storage properties compared with bare CoSb alloy, due to the combined buffering, confining and conducting effects of the in situ introduced graphene.
► We synthesize CoSb-nanocrystal/graphene composites by an in situ one-pot route.
► The composite can assemble into a novel layered hybrid nanostructure.
► The hybrid exhibits improved electrochemical properties than bare alloys.
► The graphene offers combined buffering, conducting, and confining effects.
Journal: Journal of Power Sources - Volume 202, 15 March 2012, Pages 276–283