کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1288569 1498030 2012 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Self-assembly of CoSb-nanocrystal/graphene hybrid nanostructure with improved Li-storage properties via a facile in situ solvothermal route
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Self-assembly of CoSb-nanocrystal/graphene hybrid nanostructure with improved Li-storage properties via a facile in situ solvothermal route
چکیده انگلیسی

In this work, a CoSb-nanocrystal/graphene hybrid nanostructure has been synthesized by a facile one-pot in situ solvothermal route. X-ray diffraction and X-ray photoelectron spectroscopy analyses show that the formation of CoSb alloy (CoSb or CoSb2) and the reduction of graphite oxide occur simultaneously during the one-pot solvothermal process. Scanning electron microscopy and transmission electron microscopy observations indicate that quasi-spheric CoSb (or CoSb2) nanoparticles with a size of 10–30 nm are uniformly anchored on graphene, forming a unique layered structure. The presence of graphene prevents the nanoparticles from aggregating. The attached alloy nanoparticles also hinder the restacking of the graphene sheets. The electrochemical measurements have shown that CoSb-nanocrystal/graphene nanocomposites exhibit improved electrochemical Li-storage properties compared with bare CoSb alloy, due to the combined buffering, confining and conducting effects of the in situ introduced graphene.


► We synthesize CoSb-nanocrystal/graphene composites by an in situ one-pot route.
► The composite can assemble into a novel layered hybrid nanostructure.
► The hybrid exhibits improved electrochemical properties than bare alloys.
► The graphene offers combined buffering, conducting, and confining effects.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 202, 15 March 2012, Pages 276–283
نویسندگان
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