کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1288895 973275 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Inorganic additives for passivation of high voltage cathode materials
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Inorganic additives for passivation of high voltage cathode materials
چکیده انگلیسی

The incorporation of additives designed to sacrificially react on the surface of cathode materials of lithium ion batteries has been investigated. Addition of low concentrations of inorganic additives including lithium bisoxalatoborate (LiBOB), lithium difluorooxalatoborate (LiBF2(C2O4)), and tetramethoxy titanium (TMTi) to 1 M LiPF6 in 1:1:1 EC/DEC/DMC improves the capacity retention of Li/Li1.17Mn0.58Ni0.25O2 cells cycled to 4.9 V vs. Li. Surface analysis of the cathode materials (XPS and IR) suggests that structure of the cathode surface film is modified by the presence of the additives resulting in a decrease in detrimental electrolyte oxidation reactions on the cathode surface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 196, Issue 4, 15 February 2011, Pages 2251–2254
نویسندگان
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