کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1289367 | 973297 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrocatalytic activity of perovskite La1−xSrxMnO3 towards hydrogen peroxide reduction in alkaline medium
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Perovskite-type series of compounds La1−xSrxMnO3 are synthesized by a sol–gel method using Chitosan as the gelling agent. Their catalytic activity for hydrogen peroxide electroreduction in 3.0 mol dm−3 KOH at room temperature is evaluated by means of cyclic voltammetry and chronoamperometry. Effects of annealing temperature and the ratio of La to Sr of La1−xSrxMnO3 on their catalytic performance are investigated. Among this series of compounds, La0.4Sr0.6MnO3 calcined at 650 °C exhibits the highest activity, which is comparable with Co3O4. An aluminum–hydrogen peroxide semi-fuel cell using La0.4Sr0.6MnO3 as cathode catalyst achieves a peak power density of 170 mW cm−2 at 170 mA cm−2 and 1.0 V running on 0.6 mol dm−3 H2O2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 195, Issue 19, 1 October 2010, Pages 6463–6467
Journal: Journal of Power Sources - Volume 195, Issue 19, 1 October 2010, Pages 6463–6467
نویسندگان
Guiling Wang, Yanyan Bao, Yongmei Tian, Jing Xia, Dianxue Cao,