کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1289494 | 973300 | 2009 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Palladium-polyelectrolyte hybrid nanoparticles for hydrogen sensor in fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
We prepared palladium-polyelectrolyte hybrid nanoparticles by using a metallization of polyelectrolyte. In this study, we selected polyacrylic acid (PAA) as a polyelectrolyte and reduced the palladium ions on the PAA by using ascorbic acids in order to form a unique spherically shaped mosslike hybrid nanoparticle. Palladium (Pd) can absorb hydrogen to become PdHx, and the storage of hydrogen increases the electrical resistance and volume of Pd materials. The use of this material is attracting growing interest as a reliable, cheap, ultracompact, and safe hydrogen sensor for use in fuel cells. We showed the utilization of the Pd-PAA hybrid nanoparticles as a highly sensitive hydrogen sensor that exhibited a switch response depending on volume expansion in a cyclic atmosphere exchange.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 193, Issue 1, 1 August 2009, Pages 367-370
Journal: Journal of Power Sources - Volume 193, Issue 1, 1 August 2009, Pages 367-370
نویسندگان
Satoshi Ohara, Yoshiharu Hatakeyama, Mitsuo Umetsu, Kazuyoshi Sato, Takashi Naka, Tadafumi Adschiri,