کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1290272 | 973322 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Alkali doped polybenzimidazole membrane for high performance alkaline direct ethanol fuel cell
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An anion exchange membrane for alkaline direct ethanol fuel cell (ADEFC) was prepared by doping KOH in polybenzimidazole (PBI) membrane. The distributions of nitrogen, oxygen and potassium in the membrane were analyzed by means of XRD and SEM-EDX, respectively. It was found that free or combined KOH molecules may exist in the PBI matrix, which was helpful for the ionic conductivity of PBI/KOH. Ethanol permeability through this membrane was much lower than that of Nafion®. For ADEFC based on this PBI/KOH membrane electrolyte, the power density was 3 to 6 times of the results in literatures. In addition, the micro-structure of alkali doped PBI and the interaction between KOH and PBI matrix were also speculated logically.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 182, Issue 1, 15 July 2008, Pages 95–99
Journal: Journal of Power Sources - Volume 182, Issue 1, 15 July 2008, Pages 95–99
نویسندگان
Hongying Hou, Gongquan Sun, Ronghuan He, Zhimou Wu, Baoying Sun,