کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1290596 | 973330 | 2008 | 7 صفحه PDF | دانلود رایگان |
Cobalt–phosphorous (Co–P) catalysts with a high hydrogen generation rate in alkaline sodium borohydride (NaBH4) solution are developed by electroless deposition. The microstructures of the Co–P catalysts and their catalytic activities for hydrolysis of NaBH4 are analyzed as a function of the electroless deposition conditions such as the pH and temperature of the Co–P bath. The electroless-deposited Co–P catalysts are composed of nano-crystalline Co and amorphous Co–P. The size of the nano-crystalline Co particles dispersed in amorphous Co–P matrix depends largely on the electroless deposition conditions. Moreover, Co–P catalysts with finer crystalline Co exhibit a higher hydrogen generation rate. In particular, the Co–P catalysts formed in a pH 12.5 bath at 60–70 °C exhibit the best hydrogen generation rate of 3300 ml min−1 g−1-catalyst in 1 wt.% NaOH + 10 wt.% NaBH4 solution at 30 °C, which is 60 times faster than that obtained with a Co catalyst.
Journal: Journal of Power Sources - Volume 180, Issue 1, 15 May 2008, Pages 484–490