Hydrogen storage properties of the Mg–Ti–H system prepared by high-energy–high-pressure reactive milling

Magnesium-based alloys are among the promising materials for hydrogen storage and fuel cell applications due to their high hydrogen content. In the present work, we investigated the hydrogen release/uptake properties of the Mg–Ti–H system. Samples were prepared from the mixtures of MgH2 and TiH2 in molar ratios of 7:1 and 4:1 using a high-energy-high-pressure (HEHP) mechanical ball-milling method under 13.8 MPa hydrogen pressure. Thermogravimetric analysis (TGA) showed that a relatively large amount of hydrogen (5.91 and 4.82 wt.%, respectively, for the above two samples) was released between 126 and 313 °C while temperature was increased at a heating rate of 5 °C min−1 under an argon flow. The onset dehydrogenation temperature of these mixtures, which is 126 °C, is much lower than that of MgH2 alone, which is 381 °C. The activation energy of dehydrogenation was 71 kJ mol−1, which is much smaller than that of as-received MgH2 (153 kJ mol−1) or as-milled MgH2 (96 kJ mol−1). Furthermore, the hydrogen capacity and the dehydrogenation temperature remained largely unchanged over five dehydrogenation and rehydrogenation cycles.