کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1290608 | 973330 | 2008 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Li-ion transport kinetics in LiMn2O4 thin films prepared by radio frequency magnetron sputtering Li-ion transport kinetics in LiMn2O4 thin films prepared by radio frequency magnetron sputtering](/preview/png/1290608.png)
LiMn2O4 thin films were deposited on silica glass substrates by radio frequency (RF) magnetron sputtering. The films were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Li-ion chemical diffusion coefficients D˜Li were measured by cyclic voltammetry (CV), potentiostatic intermittent titration technique (PITT), electrochemical impedance spectroscopy (EIS) and limiting current density (LCD). The D˜Li values depended on the content of Li in LixMn2O4. It was found that the D˜Li values by CV, PITT and LCD were in the order of 10−10, 10−11 and 10−12 cm2 s−1, respectively, and those by EIS were in the range of 10−9 to 10−11 cm2 s−1. The D˜Li values obtained by above methods were compared with those by an electron blocking method. It turned out that the D˜Li values by the electron blocking method were more comparable with those by EIS.
Journal: Journal of Power Sources - Volume 180, Issue 1, 15 May 2008, Pages 576–581