کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1291596 | 973366 | 2007 | 5 صفحه PDF | دانلود رایگان |
A simple and effective method for reactivation of H2S poisoned Pt-anodes is described and the feasibility of the method was examined by single cell tests and 1 kW stack tests. The performance of the H2S poisoned Pt-anode can be basically recovered by applying a high voltage pulse (1.5 V for 20 s) followed by a low voltage pulse (0.2 V for 20 s) in a single cell. During the 10 poisoning–recovery cycles, the ohmic resistance and electrochemical surface area did not change significantly. The 1 kW stack tests show that the stack performance decayed severely and the maximum power decreased to 0.366 kW (32% of the original value) after exposure to 18 ppm H2S/H2 for 2 h at 600 mA cm−2. The stack performance can be significantly recovered by applying a high voltage pulse (1.5 V for 2 min) followed by a low voltage pulse (0.2 V for 2 min) to each cell. The maximum power recovered to 1.095 kW (97.5% of the original value).
Journal: Journal of Power Sources - Volume 165, Issue 2, 20 March 2007, Pages 814–818