کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1293096 | 1498026 | 2012 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The influence of particle size and spacing on the fragmentation of nanocomposite anodes for Li batteries The influence of particle size and spacing on the fragmentation of nanocomposite anodes for Li batteries](/preview/png/1293096.png)
Experimental evidence has shown that composites comprised Si and Sn nanoparticles embedded inside a matrix are the most promising next generation anodes for Li-ion batteries. This is due to the ability of the matrix material to constrain/buffer the up to 300% volume expansion that Sn and Si undergo upon the formation of lithium rich alloys. Damage still occurs at the nanoparticle/matrix interface, and hence further materials design is required in order to commercialize such anodes. Initial theoretical works have predicted that low volume fractions and high aspect ratios of the nanoparticles result in a greater mechanical stability and hence better capacity retention. The most important design parameters, however, such as particle size and spacing have not been considered theoretically. In the present study, therefore, a gradient enhanced damage model will be employed to predict that damage during Li-insertion, is negligible when the particle size is 20 nm, and the interparticle half-spacing greater then 1.5 times the particle diameter. Furthermore, from the matrix materials considered herein graphene is predicted to be the most promising matrix, which is consistent with recent experimental data.
► We model damage in Sn and Si nanostructured anodes for Li-ion batteries.
► Different materials are considered as the matrix.
► Graphene is found to be the most promising matrix.
► Having Si/Sn diameters of 20 nm and spacing of 30 nm will limit damage.
► The theoretical prediction is in agreement with experiments.
Journal: Journal of Power Sources - Volume 206, 15 May 2012, Pages 343–348