کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1293830 973574 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polyfluorinated boron cluster-based salts: A new electrolyte for application in Li4Ti5O12/LiMn2O4 rechargeable lithium-ion batteries
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Polyfluorinated boron cluster-based salts: A new electrolyte for application in Li4Ti5O12/LiMn2O4 rechargeable lithium-ion batteries
چکیده انگلیسی

The cycling performance of Li4Ti5O12 and LiMn2O4 electrode materials has been studied in half and complete Li-ion cells with two new polyfluorinated boron cluster lithium salts (Li2B12FxH12−x) as the electrolytes. The results were compared with those obtained for the standard electrolyte, 1 M LiPF6 dissolved in ethylene carbonate and dimethyl carbonate (EC:DMC; 1:1, v/v). Three different technologies were employed for electrode fabrication: powder mixture, self-standing films and films deposited on the current collector. The latter exhibit the most interesting behavior and best performance. Cells assembled using the new electrolyte salts show excellent reversibility, coulombic efficiency, rate capability and cyclability comparable with the standard electrolyte. These features confirm the feasibility of using these polyfluorinated boron cluster-based salts as new stable Li-ion battery electrolytes.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 195, Issue 5, 1 March 2010, Pages 1479–1485
نویسندگان
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