کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1294084 | 973589 | 2009 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: New iodide-based molten salt systems for high temperature molten salt batteries New iodide-based molten salt systems for high temperature molten salt batteries](/preview/png/1294084.png)
Novel multi-component molten salt systems containing iodides, LiF–LiBr–LiI, LiF–NaBr–LiI, and LiF–LiCl–LiBr–LiI, were investigated for use as electrolytes in high temperature molten salt batteries to improve the discharge rate-capability. The iodide-based molten salts showed higher ionic conductivity (∼3 S cm−1 at 500 °C) than conventional LiCl–KCl, and had low enough melting points (below 400 °C) that can be used in practical high temperature molten salt batteries. The iodide-based salts showed instability at temperatures higher than 280 °C in dried air. The decomposition mechanism of iodide-based molten salts was discussed, and it was found that elimination of oxygen from the environment is effective to stabilize the iodide-based molten salts at high temperatures.
Journal: Journal of Power Sources - Volume 194, Issue 2, 1 December 2009, Pages 1180–1183