کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1294215 973599 2009 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The effect of doping in the electrochemical performance of (Ln1−xMx)FeO3−δ SOFC cathodes
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
The effect of doping in the electrochemical performance of (Ln1−xMx)FeO3−δ SOFC cathodes
چکیده انگلیسی

A family of iron perovskites with the general formula AFeO3−δ (A = Ln1−xMx; Ln = La, Nd and/or Pr; M = Sr or/and Ca) has been prepared keeping fixed the A cation radius 〈rA〉 and cation size mismatch to isolate the effect of divalent dopant concentration from the A-cation steric effects. The electrochemical behaviour of these compounds for their application as SOFC cathodes was evaluated by using I–V curve measurements and ac impedance spectroscopy over three electrodes electrolyte supported cells processed under identical conditions. In contrast with the bulk behaviour, trends are more difficult to observe due to microstructural effects, but results seem to indicate that the doping level, x, does not influence in a significant way the electrochemical performance of iron perovskites with identical 〈rA〉 and σ2(rA).

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 192, Issue 1, 1 July 2009, Pages 175–179
نویسندگان
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