کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1294763 | 973638 | 2008 | 9 صفحه PDF | دانلود رایگان |
Activated carbon fiber (ACF) with high specific surface area has been used as support in the preparation of Pt nanoparticles electrocatalyst (Pt/ACF) for direct alcohol fuel cells. It is found that the Pt nanoparticles on ACF are highly and homogeneously dispersed with a narrow size distribution in the range of 1.5–3.5 nm with an average size of 2.4 nm. In comparison with the commercial E-TEK Pt/C catalyst, the Pt/ACF catalyst exhibits much higher catalytic activity for methanol, ethanol and isopropanol oxidation, which are about 2.4 times as high as that of the former. The Pt/ACF catalyst is observed to be significantly more stable during the constant current density polarization and continuous cyclic voltammetry in comparison with Pt/C catalyst. Both the uniform dispersion of Pt nanoparticles and strong interactions between Pt nanoparticles and ACF are of benefit to achieve the performance improvement of Pt/ACF catalyst.
Journal: Journal of Power Sources - Volume 175, Issue 1, 3 January 2008, Pages 166–174