کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1294983 | 973647 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
NixCu6âxSn5 alloys as negative electrode materials for rechargeable lithium batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of Ni doped NixCu6âxSn5 (x = 0, 0.5, 1, 2, 4) alloys were prepared by mechanical alloying, followed by annealing at 400 °C. The Ni doped alloys show the similar structure with that of Cu6Sn5 and Ni3Sn2, which can be indexed to a hexagonal Ni2In type cell, but differ in the electrochemical performance as the anodes of Li-ion batteries. The electrochemical tests show that the cycling reversibility of NixCu6âxSn5 increases at the expense of the reversible capacity with the increasing amount of Ni content. The proper amount Ni doped alloy, Ni2Cu4Sn5 showed better cycle performance with a reversible capacity of 200 mAh gâ1 (1680 mAh mlâ1). The relative stability of the alloy was also investigated using the first-principles density-functional theory with pseudopotentials and plane wave basis (VASP).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 167, Issue 1, 1 May 2007, Pages 171-177
Journal: Journal of Power Sources - Volume 167, Issue 1, 1 May 2007, Pages 171-177
نویسندگان
Jing-jun Zhang, Yi-min Zhang, Xiao Zhang, Yong-yao Xia,