کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1295296 | 1498266 | 2015 | 7 صفحه PDF | دانلود رایگان |

• The phase transition temperature of Li7 − 3xAlxLa3Zr2O12 decreased with increasing x.
• The cubic phase exhibiting fast ionic conductivity was stabilized at x = 0.25.
• The highest ionic conductivity of 3.1 × 10− 4 S cm− 1 at 25 °C was obtained at x = 0.25 with an activation energy of 0.33 eV.
The phase formation of Li7 − 3xAlxLa3Zr2O12 was investigated by high temperature X-ray diffraction measurements. The tetragonal phase was obtained in the range of x = 0 to 0.20 and the cubic phase was formed at x = 0.25 at room temperature. A linear change of the lattice parameters was observed from x = 0 to 0.20, which is in good agreement with the systematic composition change. The solubility limit of Al3 + was determined to be x = 0.25. The reversible phase transition between the tetragonal phase and the cubic phase was observed at 640 °C for x = 0. The marked increase of ionic conductivity at the phase transition temperature is consistent with the structural change of the ordering/disordering of lithium ions. In addition, the phase transition temperature decreased with increasing x, and the cubic phase was stabilized at x = 0.25 from room temperature to 900 °C. The ionic conductivity increased with x and the highest ionic conductivity of 3.1 × 10− 4 S cm− 1 at 25 °C was obtained for x = 0.25. Al3 + substitution introduces lithium vacancies, which has a strong influence on the phase transition between the tetragonal and cubic phases. The results obtained here suggest that control of the lithium vacancies is the key to obtain a fast lithium-conducting phase.
Journal: Solid State Ionics - Volume 277, September 2015, Pages 23–29