کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1295296 1498266 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase formation of a garnet-type lithium-ion conductor Li7 − 3xAlxLa3Zr2O12
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Phase formation of a garnet-type lithium-ion conductor Li7 − 3xAlxLa3Zr2O12
چکیده انگلیسی


• The phase transition temperature of Li7 − 3xAlxLa3Zr2O12 decreased with increasing x.
• The cubic phase exhibiting fast ionic conductivity was stabilized at x = 0.25.
• The highest ionic conductivity of 3.1 × 10− 4 S cm− 1 at 25 °C was obtained at x = 0.25 with an activation energy of 0.33 eV.

The phase formation of Li7 − 3xAlxLa3Zr2O12 was investigated by high temperature X-ray diffraction measurements. The tetragonal phase was obtained in the range of x = 0 to 0.20 and the cubic phase was formed at x = 0.25 at room temperature. A linear change of the lattice parameters was observed from x = 0 to 0.20, which is in good agreement with the systematic composition change. The solubility limit of Al3 + was determined to be x = 0.25. The reversible phase transition between the tetragonal phase and the cubic phase was observed at 640 °C for x = 0. The marked increase of ionic conductivity at the phase transition temperature is consistent with the structural change of the ordering/disordering of lithium ions. In addition, the phase transition temperature decreased with increasing x, and the cubic phase was stabilized at x = 0.25 from room temperature to 900 °C. The ionic conductivity increased with x and the highest ionic conductivity of 3.1 × 10− 4 S cm− 1 at 25 °C was obtained for x = 0.25. Al3 + substitution introduces lithium vacancies, which has a strong influence on the phase transition between the tetragonal and cubic phases. The results obtained here suggest that control of the lithium vacancies is the key to obtain a fast lithium-conducting phase.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 277, September 2015, Pages 23–29
نویسندگان
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