کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1295487 | 1498402 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microstructural and electrical characterisation of melt grown high temperature protonic conductors
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Microstructural and electrical characterisation of melt grown high temperature protonic conductors Microstructural and electrical characterisation of melt grown high temperature protonic conductors](/preview/png/1295487.png)
چکیده انگلیسی
High temperature protonic conductors of SrCe1âxYxO3âδ and Sr3Ca1+xNb2âxO9âδ were fabricated by directional solidification to produce model microstructures. Elongated cells exhibited ã100ã direction parallel to the growth axis; low degree of disorientation was observed between the cells. In the simple perovskite SrCe1âxYxO3âδ aluminum contamination caused the formation of intergranular second phase. Nuclear microprobe revealed that the second phase was enriched with hydrogen. Impedance spectroscopy revealed that the protons at grain boundaries have a lower mobility than within the cells. The cation distribution was not uniform in the complex perovskite. Inverse gradients in Ca2+ and Nb5+ were observed from the core to the shell of the cells. The Nb5+ substitution decreased from x = 0.12 at the core to 0.07 at the shell. Higher Nb5+/Ca2+ ratio at the shell decreased the protonic conductivity. Nanodomain were observed in both perovskite compositions; they differentiate by a 90° rotation of the direction of oxygen cage tilting. In the complex perovskite, stoichiometric domains with an ordered distribution of Nb5+ and Ca2+ were surrounded by nonstoichiometric domains with a random distribution of these cations. Further work and analyses are required to understand the mechanism of proton transfer within domains and across domain interfaces.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 26â32, 31 October 2006, Pages 2339-2345
Journal: Solid State Ionics - Volume 177, Issues 26â32, 31 October 2006, Pages 2339-2345
نویسندگان
Marie-Helene Berger, Ali Sayir, Fred Dynys, Pascal Berger,