کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1295538 1498402 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High lithium ion conductivity glass-ceramics in Li2O-Al2O3-TiO2-P2O5 from nanoscaled glassy powders by mechanical milling
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
High lithium ion conductivity glass-ceramics in Li2O-Al2O3-TiO2-P2O5 from nanoscaled glassy powders by mechanical milling
چکیده انگلیسی
Mechanical milling (MM) has been used to prepare the nanosized Li1.4Al0.4Ti1.6(PO4)3 (denoted LATP) glassy powders, which was converted into glass-ceramics through thermal treating at 700-1000 °C. The XRD, TEM, FESEM and ac impedance techniques were used to characterize the products. The results showed that completely amorphous products were prepared by MM for 40 h, and single-phase LiTi2(PO4)3-type structured glass-ceramics were obtained by further heat treatment. The lithium ion conductivity of the glass-ceramics increased with the growth of the crystalline phase and decrease of the grain size. The highest bulk conductivity (σb) of 1.09 × 10− 3 S cm− 1 with an energy of activation as low as 0.28 eV was obtained at room temperature for the specimen treated at 900 °C for 6 h. The high conductivity, easy fabrication and low cost make the LATP glass-ceramics promising to be used as inorganic solid electrolyte for all-solid-state Li-ion rechargeable batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 26–32, 31 October 2006, Pages 2611-2615
نویسندگان
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