کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1296083 | 1498302 | 2013 | 6 صفحه PDF | دانلود رایگان |

Nd-Nickelate (NNO), Nd1.95NiO4 + δ, an alternative solid oxide fuel cell cathode material, has been imaged and mapped in 3D using synchrotron-based x-ray nanotomography. The NNO cathode material, which suffered from silicon contamination during fabrication, was found to contain the desired NNO, plus two distinct poisoning phases. The likely composition and description of the poisoning phases are presented, as well as a detailed description of the microstructural mapping and material characterization. The insulating poisoning phases are likely to have deleterious implications for the cell, as they have a tendency to form a coating layer on the NNO surface, significantly decreasing its active area. Additional losses may be expected due to the poisoning phases inhibiting ionic and electronic transport pathways, increasing cathode polarization resistance.
► Investigated 3-D microstructure of neodymim nickelate for fuel cell cathode.
► Three dimensional imaging performed using synchrotron-based x-ray nanotomography.
► Silicon contamination during fabrication created significant poisoning phases.
► 3-D imaging reveals detailed detrimental phases.
► Poisoning phases are expected to be detrimental to electrode performance.
Journal: Solid State Ionics - Volume 237, 15 April 2013, Pages 16–21