Defect structure and electrical conductivity in the pseudo-binary system Bi3TaO7–Bi3NbO7

A study of electrical and structural characteristics of compositions in the Bi3Ta1 − xNbxO7 system, using X-ray and neutron powder diffraction and AC impedance spectroscopy, is presented. The electrical conductivity increases with increasing niobium content. A full solid solution is observed which adopts an incommensurately ordered pseudo-cubic fluorite structure (type II). Analysis of the defect structure of the x = 0.50 composition shows chains of niobate/tantalate octahedra as a likely structural motif. A small degree of non-linearity in the thermal expansion of the cubic subcell lattice parameter is observed.

► Bi3Ta1 − xNbxO7 system exhibits type II incommensurate structure.
► Defect structure is consistent with chains of tantalate/niobate octahedra.
► Lattice parameter thermal expansion correlated with oxide ion distribution changes.