کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1297503 | 1498403 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Correlation of defect structure and ionic conductivity in δ-phase solid solutions in the Bi3NbO7-Bi3YO6 system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Defect structure and conductivity behaviour are discussed in the solid solution Bi3Nb1âxYxO7âx(0.0 â¤Â x â¤Â 1.0). Investigations were carried out using a combination of ac impedance spectroscopy and powder X-ray and neutron diffraction. Low temperature conductivity and activation energy both increase as a function of x. The former is attributed to an increase in oxide ion vacancy concentration, whereas the latter is due a redistribution of oxide ion vacancies as determined by neutron diffraction measurements. The defect structures at room temperature and 800 °C are presented. Curvature in Arrhenius plots of conductivity throughout the composition range is associated with a temperature dependent redistribution of oxide ions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 177, Issues 19â25, 15 October 2006, Pages 1761-1765
Journal: Solid State Ionics - Volume 177, Issues 19â25, 15 October 2006, Pages 1761-1765
نویسندگان
I. Abrahams, A. Kozanecka-Szmigiel, F. Krok, W. Wrobel, S.C.M. Chan, J.R. Dygas,