کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1298008 1498369 2008 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Thermodynamic modeling of the cerium–yttrium–oxygen system
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Thermodynamic modeling of the cerium–yttrium–oxygen system
چکیده انگلیسی

The published data for the thermochemical properties and phase relationships of the cerium–yttrium–oxygen system have been critically examined. The thermodynamic properties of the phases are described using “compound energy formalism” for the various solid phases and an associate solution model for liquid phase. The model parameters have been optimized by least-squares fit to the selected experimental information of different kind (phase diagram data, calorimetric data, and equilibrium oxygen pressures) using the CALPHAD method. A self-consistent set of Gibbs energy functions describing the Ce–Y–O system has been obtained for the first time. The models are simple to be compatible with the standard Gibbs energy minimization procedure, but provide enough flexibility to account for the crystal structure, defect chemistry, and thermodynamic properties of phases in the Ce–Y–O system. The backward compatibility of the refined parameters with experimental data has been demonstrated by calculation of phase and property diagrams.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 179, Issues 33–34, 15 October 2008, Pages 1902–1911
نویسندگان
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