کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1305785 975049 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3n− family
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3n− family
چکیده انگلیسی


• Hydrothermal syntheses of bimetallic vanadium arsonate materials.
• Structures of vanadium arsonate clusters.
• Mixed dimensional vanadium arsonate material.

Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n− family. Under the conditions of this study the one-dimensional [Cu(phen)VO2(O3AsC6H5)(HO3AsC6H5)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO2(O3AsC6H5)(HO3AsC6H5)][Cu(bpy)V2O4(O3AsC6H5)2] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine)

Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n− family. The unique mixed dimensional structure of [{Cu(bpy)}2V3O6(C6H5AsO3)3(C6H5AsO3H)] is shown.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 409, Part B, 1 January 2014, Pages 296–301
نویسندگان
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