کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306525 | 975094 | 2011 | 6 صفحه PDF | دانلود رایگان |
The nature of the bonding in acetohydroxamic acid, copper acetohydroxamate and copper n-octanohydroxamate has been investigated by chemical analysis, XPS, FTIR and Raman spectroscopy. Vibrational spectra show the acid to be in the keto Z conformation as was previously established for the n-octano homologue. Chemical analysis established that the copper compounds have a copper:hydroxamate stoichiometry of 1:1. XPS confirms that they are CuII compounds. The absence of vibrational spectral bands that were previously identified with N–H vibrations for n-octanohydroxamic acid and its potassium compound, together with the presence of a CN stretch band that shifts when the nitrogen is labelled with 15N, confirms that the hydroxamate moieties in the CuII compounds are in the enol configuration. Some interaction between Cu and N is indicated by the spectra and could explain the 1:1 stoichiometry of the CuII hydroxamates investigated.
Chemical analysis, XPS, FTIR and Raman spectroscopy have shown that copper acetohydroxamate and copper n-octanohydroxamate are CuII compounds with a 1:1 copper:hydroxamate stoichiometry. Whereas the corresponding hydroxamic acids have the keto Z conformation, the copper compounds are in the enol configuration.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 365, Issue 1, 15 January 2011, Pages 65–70