کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1306602 | 1499160 | 2015 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: [Li2{CH2S(O)Ph}2(TMEDA)2] – An α-sulfinyl-functionalized methyllithium carbenoid [Li2{CH2S(O)Ph}2(TMEDA)2] – An α-sulfinyl-functionalized methyllithium carbenoid](/preview/png/1306602.png)
• The carbenoid reactivity of the lithiated sulfoxide [Li2{CH2S(O)Ph}2(TMEDA)2] (1) is reported.
• Temperature dependent NMR measurements of 1 revealed an intermolecular dynamic process.
• The aggregation state of 1 in solution was measured by means of 1H DOSY NMR spectroscopy.
The aggregation state of the α-sulfinyl-functionalized methyllithium compound [Li2{CH2S(O)Ph}2(TMEDA)2] (1) in solution and its carbenoid reactivity is presented. Temperature dependent NMR measurements of 1 in THF-d8 revealed the presence of an intermolecular dynamic process (dimer–monomer–dimer equilibrium) with a Gibbs free energy of activation of about 45 kJ/mol. 1H DOSY NMR measurements exhibited that in THF-d8 solution the coligand TMEDA is partially cleaved off. Furthermore, the decomposition of 1 in THF-d8 (room temperature, 96 h) led to the formation of ethylene and PhSSPh. In refluxing toluene 1 decomposed with formation of ethylene, PhSSPh, xylenes, ethylbenzene, n-propylbenzene and isopropylbenzene. The dimerizing α-elimination yielding ethylene and the C–H insertion reactions observed in boiling toluene give proof of a carbenoid reactivity of 1.
The aggregation state of the α-sulfinyl-functionalized methyllithium compound [Li2{CH2S(O)Ph}2(TMEDA)2] in solution and its carbenoid reactivity is presented.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 429, 1 April 2015, Pages 30–33