کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1306617 1499160 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel synthesis and characterization of Fe3O4@silica–palladium nanocatalyst: A highly active and reusable heterogeneous catalyst for Heck cross-coupling reactions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Novel synthesis and characterization of Fe3O4@silica–palladium nanocatalyst: A highly active and reusable heterogeneous catalyst for Heck cross-coupling reactions
چکیده انگلیسی


• A novel method for synthesis of Pd nanocatalyst modified Fe3O4 MNPs was introduced.
• The surface of Fe3O4 MNPs was modified with amine and vinyl precursors of silica.
• The Pd nanocatalysts are formed by direct contact of modified Fe3O4 MNPs with Pd precursor.
• No additional chemical reducers were needed to produce Pd nanocatalysts.
• The catalytic activity of Pd nanocatalysts was investigated in Heck coupling reactions.

A novel method for synthesis of palladium nanocatalyst on Fe3O4 magnetic nanoparticles was introduced. For this purpose, the surface of magnetic nanoparticles was modified with two different precursors of silica which produced amine and vinyl functional groups on the surface of magnetic nanoparticles. The palladium nanocatalysts were formed on silica shell by direct contact of modified magnetic nanoparticles with the palladium precursor without special requirement of any additional chemical reducer. The nanocatalysts were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), vibrating sample magnetometry (VSM) and thermo-gravimetric analysis (TGA). The catalytic activity of supported palladium nanocatalysts was investigated in Heck coupling reactions of a series of aryl halides and olefins. Under appropriate conditions, all reactions afforded the desired products in relatively excellent yields.

A facile method for synthesis of palladium nanocatalyst on amino-vinyl functionalized Fe3O4 magnetic nanoparticles was introduced. The catalytic activity of supported palladium nanocatalysts was investigated in Heck coupling reactions of a series of aryl halides and olefins.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 429, 1 April 2015, Pages 132–137
نویسندگان
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