Reactivity of tri(2-furyl)phosphine (PFu3) with [Mn2(CO)10-n(NCMe)n] (n = 0-2): X-ray Structure of mer-[Mn(CO)3(η1-C4H3O)(PFu3)2]

► Reactions of tri(2-furyl)phosphine (PFu3) with [Mn2(CO)10−n(NCMe)n] (n = 0-2). ► Synthesis and characterization of PFu3 substituted manganese complexes. ► Synthesis and X-ray structure determination of mer-[Mn(CO)3(η1-C4H3O)(PFu3)2].