کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1307564 | 975147 | 2008 | 6 صفحه PDF | دانلود رایگان |
The synthesis and structural characterization of the copper salts [Cu2(2-Boc-benzoate)4(dme)2] (1), [Cu(2-Boc-benzoate)2(tmeda)] (2), [Cu2(2-Boc-benzoate)2(dppm)] (3), [Cu(2-Boc-nicotinate)(PPh3)2] (4), [Cu2{2-Boc-5,6-anhydride-naphthylcarboxylate}2(dppm)2] (5) [dme = 1,2-dimethoxyethane, dppm = bis(diphenylphosphino)methane, tmeda = N,N′-tetramethylethylenediamine, Boc = tert-butoxycarbonyl] prove that cyclic organic anhydrides and dianhydrides readily insert into the Cu–O bond of [CuOtBu] forming carboxylate ligands with ester functionalities in the ligand periphery. [Sb(CO2Ph-o-CO2Me)2(OMe)(tmeda)] (6) was synthesised by insertion reaction of Sb(OMe)3 with phthalic anhydride.
The synthesis and structural characterization of new copper carboxylates and an antimony complex obtained by insertion reactions from organic anhydrides into the metal bond of metal alkoxides is reported.Figure optionsDownload as PowerPoint slide
Journal: Inorganica Chimica Acta - Volume 361, Issue 1, 1 January 2008, Pages 43–48