کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1307739 975152 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
One-step preparation of dithiocarboimidate ligands by addition of phenylisothiocyanate to tetrathiomolybdate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
One-step preparation of dithiocarboimidate ligands by addition of phenylisothiocyanate to tetrathiomolybdate
چکیده انگلیسی

Reaction of C6H5NCS with MoS42- led to the formation of a dinuclear complex of molybdenum(V) with two dithiocarboimidate ligands, (NEt4)2[Mo2(S)2(μ-S)2(η2-S2CN(C6H5))2] · 0.5CO(CH3)2. The crystallization of 1 is systematically accompanied by the formation of 4-phenyl-3,5-diphenylimino[1,2,4]-dithiazolidine [(C6H5)3N3C2S2] (2). The two compounds have been structurally characterized by XRD and a reaction scheme is proposed.

Syntheses in one-step and characterizations of (NEt4)2[Mo2(S)2(μ-S)2(η2-S2CN(C6H5))2] · 0.5CO(CH3)2 (1) and of 4-phenyl-3,5-diphenylimino[1,2,4]-dithiazolidine[(C6H5)3N3C2S2] (2) are presented.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 360, Issue 10, 2 July 2007, Pages 3436–3441
نویسندگان
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