Three zinc(II) complexes constructed from aromatic dicarboxylate and 1,4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl)methyl)benzene: Syntheses, crystal structures and luminescent properties

To investigate the effect of organic anions on the coordination frameworks, we synthesized three new complexes, namely, Zn(DPA)(bpimb)0.5(H2O) (1), Zn(BDC)(bpimb)0.5 (2) and Zn2(SDBA)2(bpimb)·H2O (3) (H2DPA = diphenic acid; H2BDC = isophthalic acid; H2SDBA = 4,4′-dicarboxybiphenylsulfone), which were obtained by the reactions of 1,4-bis((2-(pyridin-2-yl)-1H-imidazol-1-yl)methyl)benzene (bpimb) as main ligand, and several aromatic polycarboxylate as organic anions with Zn(NO3)2·6H2O. Single-crystal structure analysis shows that complex 1 is a one-dimensional chain structure, which is further interlinked into a higher-dimensional supramolecular framework by hydrogen-bonding interactions. In 2, BDC bridge Zn(II) atoms to give dimeric units, which are further linked by bpimb ligands to form sql nets. In 3, SDBA ligands and bpimb ligands connect Zn(II) ions into catenane-like two-dimensional layers. These catenane-like two-dimensional layers stack in an ABAB fashion to form a 3D supramolecular network. The distinct structures indicate three kinds of carboxylic ligands with different lengths and angles play fundamental roles in the formation of the final products. In addition, the luminescence measurements reveal that three complexes exhibit strong fluorescent emissions in the solid state at room temperature.

Three coordination polymers, [Zn(DPA)(bpimb)0.5(H2O) (1), Zn(BDC)(bpimb)0.5 (2) and Zn2(SDBA)2(bpimb)·H2O (3), were synthesized. Complex 1 is a one-dimensional chain structure. Complex 2 has two-dimensional sql nets, while complex 3 features a 2-fold parallel interpenetrating net with (4,4) topology. Thermal and luminescent properties of three complexes have also been investigated.Figure optionsDownload as PowerPoint slide